Sunday 30 April 2017

Making a secondary amine



Making a secondary amine
The reaction doesn't stop at a primary amine. The ethylamine also reacts with bromoethane 
- in the same two stages as before.


In the first stage, you get a salt formed - this time, diethylammonium bromide. 
Think of this as ammonium bromide with two hydrogens replaced by ethyl groups.
There is again the possibility of a reversible reaction between this salt and excess
 ammonia in the mixture.


The ammonia removes a hydrogen ion from the diethylammonium ion to leave a
 secondary amine - diethylamine. A secondary amine is one which has two alkyl groups 
attached to the nitrogen.


This time there isn't any hydrogen left on the nitrogen to be removed. The reaction stops
 here.


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